PROCESS FOR MANUFACTURING 6XXX ALUMINUM ALUMINUM THIN ALLOYS WITH HIGH SURFACE QUALITY

专利摘要:
The subject of the invention is a process for manufacturing an aluminum sheet of the 6xxx series comprising the following steps: homogenization of an ingot made from an aluminum alloy of the 6XXX series; cooling the homogenized ingot at a cooling rate in the range of 150 ° C / h to 2000 ° C / h directly at the starting temperature of the hot rolling; hot rolling of the ingot to a final thickness and winding to the final thickness and a hot rolling exit temperature with conditions to obtain at least 90% recrystallization while controlling the hot rolling temperatures , especially the relationship between the hot rolling start temperature and the hot rolling output temperature, and / or controlling the grain size after winding; cold rolling to obtain a cold rolled thin sheet. The process of the invention is particularly useful for the manufacture of thin sheets for the automotive industry which combine a high tensile yield strength and a formability suitable for cold drawing operations, as well as that an excellent surface quality.
公开号:FR3076837A1
申请号:FR1850349
申请日:2018-01-16
公开日:2019-07-19
发明作者:Laurent BOISSONNET；Jean-Philippe Masse；Gilles Guiglionda
申请人:Constellium Neuf Brisach SAS；
IPC主号:

专利说明:

METHOD FOR MANUFACTURING HIGH-SURFACE QUALITY ALUMINUM 6XXX THIN SHEET
DESCRIPTION
FIELD OF THE INVENTION
The present invention relates to a process for manufacturing thin sheets of aluminum alloy 6XXX, particularly useful for the automotive industry.
BACKGROUND OF THE INVENTION
Different aluminum alloys are used in the form of sheets or blanks for applications in the automotive field. Among these alloys, the AA6xxx series aluminum alloys, such as the AA6016-T4 alloy, combine interesting chemical and mechanical properties such as hardness, resistance or even corrosion resistance. In addition to the above-mentioned requirements, another imperative implies that the aluminum alloys used for automotive components do not exhibit unacceptable and / or deleterious surface defects - lineage or "roping" - which appear on the surface of the components produced. from thin stamped or folded aluminum sheets. The lineage appears in the rolling direction only under the effect of sufficient transverse deformation, such as that which occurs during typical stamping or shaping operations. New surface quality criteria have recently appeared, based on the analysis of digital images, in particular the possible directional roughness of the surface, relevant to the appearance of the final product. This type of process has for example been explained by A. Guillotin et al. (MATERIALS CHARACTERIZATION
61 (2010) 1119-1125) or the VDA (Verband Der Automobilindustrie, association of the German automobile industry) Recommendation 239-400, July 2017. These properties generally make AA6xxx aluminum alloys the materials of choice for automobile industry. In order to meet the constant increase in the applications of these thin sheets and the surface quality requirements imposed by the automotive industry, it is imperative to improve the speed of the manufacturing process for these products for a surface quality demanded by customers. In fact, although the current process includes several heat treatments which have proven to be effective in terms of surface quality and formability, it can be long and costly.
Patent US6652678 describes a process for converting an aluminum alloy ingot of the 6000 series into a self-baking thin sheet. This process consists in subjecting the ingot to a homogenization treatment in two stages, first at a temperature of at least 560 ° C, then at a temperature between 450 ° C and 480 ° C. It then consists of hot rolling the homogenized ingot at a starting temperature between 450 ° C and 480 ° C, then at a finishing temperature between 320 ° C and 360 ° C. A hot-rolled thin sheet is thus obtained, the cube recrystallization component of which is exceptionally low.
Patent application US2016 / 0201158 describes a process for manufacturing a thin sheet of aluminum alloy of the 6xxx series comprising the following steps: casting an aluminum alloy of the 6xxx series to form an ingot; homogenization of the ingot; hot rolling of the ingot in order to produce a hot rolled intermediate product, then: a) after winding at the exit temperature, immediate placement in an annealing furnace, or b) after winding at the exit temperature, cooling to room temperature then placing in an annealing, annealing, cold rolling oven, the thin sheet thus obtained is then subjected to a continuous annealing heat treatment process and dissolving. The application details the problems related to the self-baking process.
Patent application EP1375691 (A9) describes a method for manufacturing a thin sheet laminated from an aluminum alloy of the 6000 type containing Si and Mg as main alloying elements, which consists in subjecting an ingot to a homogenization treatment, to cool it to a temperature below 350 ° C at a cooling rate greater than or equal to 100 ° C / h, optionally to room temperature, to heat it again to a temperature between 300 and 500 ° C and then subjecting it to hot rolling; the hot-rolled product is subjected to cold rolling, and the cold-rolled thin sheet is subjected to a solution treatment at a temperature of 400 ° C. or more, followed by quenching.
Patent application EP0786535 (A1) describes a process according to which an aluminum alloy ingot containing not less than 0.4% by weight and less than 1.7% by weight of Si, not less than 0.2% by weight and less than 1.2% by weight of Mg, the balance consisting of Al and unavoidable impurities, is homogenized at a temperature not less than 500 ° C. The product thus obtained is cooled from a temperature not lower than 500 ° C to a temperature in the range between 350 and 450 ° C, and the starting point of which allows hot rolling, the hot rolling step ending at a temperature in the range of 200 to 300 ° C. The product thus obtained is subjected to cold rolling at a reduction ratio of not less than 50% immediately before its solution treatment. The cold-rolled product is then subjected to a solution treatment during which it is maintained at a temperature in the range between 500 and 580 ° C. at a temperature increase rate not less than 2 ° C./ s for no more than 10 minutes. The product thus obtained is subjected to hardening during which it is cooled to a temperature not higher than 100 ° C at a cooling rate not lower than 5 ° C / s.
As regards the formability of thin sheets of aluminum alloy, it has been indicated that it is a function of the size of the particles, such as the particles Al-Fe-Si, Mg-Si, etc. which form precipitates in the alloy, and the texture of the alloy. For example, patent applications JP 2012-77319, JP 2006-241548, JP 2004-10982, JP 2003-226926 propose methods which take into account the control of the size and the distribution of these particles, the control of the texture and the resulting r-value.
On the other hand, in parallel with the proposals relating to the improvement of the fitness for shaping as described above, several initiatives aiming to improve the resistance to lineage in relation to the quality of the aspect after setting fit have also been reported. According to the latter, the appearance of the lineage is linked to the recrystallization behavior of the material. And as a measure intended to limit the appearance of lineage, it has been proposed to control recrystallization at the stage of production of thin sheets by means of hot rolling or a similar process carried out after homogenization of the alloy ingot.
As practical measures in favor of such an improvement in tensile strength, patents JP2823797 and JP3590685 limit the magnification of the crystalline grain during hot rolling by mainly setting the starting temperature of hot rolling to a value relatively low at 450 ° C, and aim to control the structure of the material after the subsequent cold work hardening and solution treatment. Patent application JP2009-263781 describes the implementation of a rolling at different circumferential speeds in the hot zones and a rolling at different circumferential speeds in the cold zones after the hot rolling. Here, patent JP3590685, and patent applications JP2012-77318 and JP2010-242215 propose to carry out an intermediate annealing after the hot rolling, or to carry out an intermediate annealing after the execution of a short cold rolling.
Patent application JP2015-67857 describes a process for manufacturing aluminum alloy thin sheet based on AlMg-Si for an automobile panel characterized by the following elements: an ingot composed of Si: 0.4- is prepared 1.5% by weight, Mg: 0.2-1.2% by weight, Cu: 0.001-1.0% by weight, Zn: 0.5% or less, Ti: less than 0.1% by weight, B: 50 ppm or less, and one or more of two of the following: Mn: 0.30% wt or less, Cr: 0.20% wt or less, Zr: 0.15% or less, the balance being made up of 'Al and unavoidable impurities. The ingot thus obtained is subjected to a homogenization treatment at a temperature above 450 ° C, cooled to less than 350 ° C at a cooling rate greater than 100 ° C / h, and again heated to a temperature between 380 ° C and 500 ° C, then hot rolling is carried out to initiate the rolling process, and a plate 4 to 20 mm thick is produced. The said plate is subjected to a cold reduction, so that the reduction rate of its thickness is greater than 20% and that its thickness is greater than 2 mm, to an intermediate annealing at a temperature between 350 and 580 ° C., to an additional cold reduction, then to a solution treatment at a temperature in the range between 450 and 600 ° C. It is then rapidly cooled to a temperature below 150 ° C at an average cooling rate greater than 100 ° C / minute, then subjected to a heat treatment within 60 minutes following the rapid cooling process in order to keep it within the range between 40 and 120 ° C for 10 to 500 minutes.
The automotive industry therefore needs an improved method, in particular offering high productivity, for the production of thin sheets of aluminum alloy of the 6xxx series, which combine a high yield strength with good formability, suitable for cold stamping operations, as well as excellent surface quality and high resistance to corrosion.
SUMMARY OF THE INVENTION
The subject of the invention is a method of manufacturing a thin aluminum sheet of the 6xxx series comprising the following steps:
- homogenization of an ingot made from an aluminum alloy of the 6XXX series preferably consisting of the following elements, in weight content: 0.3 to 1.5% of Si, 0.1 to 1.2% of Mg and 0.5% or less of Cu, Mn 0.03 0.5% and / or Cr 0.01 - 0.4%, Fe 0.03 to 0.4%, Zn at most 0.5% , V at most 0.2%, Zr at most 0.2%, Ti at most 0.1%, the balance consisting of aluminum and inevitable impurities of at most 0.05% and 0.15 % in total,
- cooling of the homogenized ingot at a cooling rate located in the range between 150 ° C / h and 2000 ° C / h directly to a starting temperature of hot rolling (HRST),
hot rolling of the ingot to a final thickness and winding at the final thickness and at an exit temperature from hot rolling with conditions allowing at least 90% recrystallization to be obtained, said HRST being between 350 ° C and 450 ° C and the exit temperature of the hot rolling being equal to or greater than 300 ° C and between 1.2 * HRST - 135 ° C and
1.2 * HRST - 109 ° C and / or adjusted so as to obtain an average grain size in the L / TC section between mid-thickness and a quarter of the thickness, according to the intercept method of the standard ASTM E-112, less than 160 µm in the longitudinal direction,
- cold rolling in order to obtain a cold-rolled thin sheet.
DESCRIPTION OF THE INVENTION
All the aluminum alloys referred to below are designated, unless otherwise stated, according to the rules and designations defined by the “Aluminum Association” in the “Registration Record Sériés” which it regularly publishes.
The metallurgical states in question are designated according to European standard EN-515.
All alloy compositions are supplied in weight content (wt%).
The inventors have observed that the process for producing aluminum alloys of the 6xxx series according to the prior art can be improved without compromising the strength, the formability properties and the corrosion resistance, and this with improved surface quality.
According to the invention, an ingot is prepared by casting, generally by semi-continuous casting, using aluminum alloys of the 6xxx series. The thickness of the ingot is preferably at least 250 mm, or at least 350 mm, and it is preferably a large caliber ingot with a thickness of at least 400 mm, or even at least 500 mm or 600 mm in order to improve the productivity of the process. The ingot preferably has a width between 1000 and 2000 mm and a length between 2000 and 8000 mm.
The Si content is between 0.3% by weight and 1.5% by weight.
Si is an addition element which forms the basis of the series of alloys of the present invention and which, together with Mg, contributes to improving the strength. When the Si content is less than 0.3% by weight, the above-mentioned effect may prove to be insufficient, while a content greater than 1.5% by weight can cause the appearance of large particles of Si and large particles based on Mg-Si, and lead to a decrease in the ability to bend. Therefore, the Si content is preferably defined in a range from 0.3 to 1.5 wt%. A minimum Si content of 0.55%, or 0.6% or 0.7% or 0.8% or 0.9% or 1.0% or 1.1% may be advantageous. A maximum Si content by weight of 1.4%, or 1.3% or 1.2% or 1.1% may be advantageous.
Mg is also an addition element which forms the basis of the series of alloys which is the object of the present invention and which, together with Si and Mg, contributes to improving the resistance. The Mg content is between 0.1% w / w and 1.2% w / w. When the Mg content is less than 0.1 wt%, the formation of GP zones, which contribute to the improvement in resistance, decreases due to precipitation hardening when the paint is cured, and the improvement resistance may therefore be insufficient. On the other hand, a content greater than 1.2% by weight can cause the appearance of large particles based on Mg-Si and lead to a decrease in the ability to bend. A minimum weight content of Mg of 0.15%, or 0.20% or 0.25% or 0.30% or 0.35% or 0.40% or 0.45% or 0.50% or 0.55% may be advantageous. A maximum Mg content by weight of 0.90%, or 0.85% or 0.80% or 0.75% or 0.70% or 0.65% or 0.60% or 0.55% can be advantageous.
There are certain advantageous combinations of Si and Mg contents. In one embodiment, the weight content of Si is between 1.1% and 1.5% and preferably between 1.2% and 1.4%, and the weight content of Mg is between 0.1% and 0.5% and preferably between 0.2% and 0.4%. In another embodiment, the Si content by weight is between 0.7% and 1.1% and preferably between 0.8% and 1.0%, and the Mg content by weight is between 0.2 % and 0.6% and preferably between 0.3% and 0.5%. In yet another embodiment, the weight content of Si is between 0.55% and 0.95% and preferably between 0.65% and 0.85%, and the weight content of Mg is between 0, 45% and 0.85% and preferably between 0.50% and 0.75%.
The parameters of the process of the present invention which make it possible to obtain a high surface quality have been defined for a Cu content by weight of 0.5% at most, preferably 0.2% at most and preferably 0.1 % maximum.
Mn and Cr are effective elements for improving resistance, refining the crystal grain and stabilizing the structure. When the Mn content by weight is less than 0.03% and / or when the Cr content by weight is less than 0.01%, the above-mentioned effect is insufficient. On the other hand, a weight content of Mn greater than 0.5% and / or a weight content of Cr greater than 0.4% can not only cause saturation of the above effect, but also the generation of compounds multiple intermetals which could have a negative effect on the formability, in particular the crimping. Consequently, the weight content of Mn is defined in a range between 0.03 and 0.5% and / or in Cr in a range between 0.01 and 0.4%, respectively. Preferably, the weight content of Mn is defined in a range between 0.04 and 0.3% and / or in Cr in a range between 0.02 and 0.3%, respectively.
Fe is also an effective element for improving the strength and refining of the crystal grain. A Fe content by weight of less than 0.03% may not produce a sufficient effect, while a Fe content by weight of more than 0.4% may cause the formation of multiple intermetallic compounds which may cause a decrease in ability at bending. Consequently, the Fe content is defined in a range between 0.03% by weight and 0.4% by weight and preferably between 0.1% by weight and 0.3% by weight. In one embodiment, the weight content of Fe is less than 0.2%. Zn can be added up to 0.5% by weight and preferably up to 0.2% by weight without departing from the advantages of the invention. In one embodiment, Zn is one of the unavoidable impurities.
V can be added up to 0.2% by weight and preferably up to 0.1% by weight without departing from the advantages of the invention. In one embodiment, the V is one of the inevitable impurities.
Zr can be added up to 0.2% by weight and preferably up to 0.1% by weight without departing from the advantages of the invention. In one embodiment, Zr is one of the unavoidable impurities.
Grain refining elements such as Ti, T1B2 or other similar elements are generally added with a total Ti content by weight of up to 0.1% and preferably between 0.01 and 0.05 %.
The balance consists of aluminum and unavoidable impurities of at most 0.05% each and 0.15% in total, by weight content. The aluminum alloy compositions preferred for the invention are the following: AA6005, AA6022 and AA60.16.
In a first preferred embodiment of the invention, said series aluminum alloy la 6xxx consists of the following elements, in% by weight: Si: 0.55 - 0.95; Mg: 0.45-0.85; Cu: at most 0.1; Mn: 0.03 to 0.1; Fe: 0.05-0.20; Ti: at most 0.05, the remainder consisting of aluminum and unavoidable impurities of at most 0.05 each and 0.15 in total.
In a second preferred embodiment of the invention, said aluminum alloy of the 6xxx series consists of the following elements, in% by weight: Si: 0.7 - 1.5; Mg: 0.1-0.8; Cu: at most 0.2; Mn: 1.2 - 1.6; Cu: at most 0.03; Mn: at most 0.7; Zn: at most 0.3; Fe: at most 0.4; Ti: at most 0.1, the remainder consisting of aluminum and unavoidable impurities of at most 0.05 each and 0.15 in total, and preferably Si: 0.8 - 1.1; Mg: 0.2-0.6; Cu: at most 0.1; Mn: 0.03 - 0.2; Fe 0.1 - 0.3; Ti: at most 0.05, the balance consisting of aluminum and unavoidable impurities of at most 0.05 each and 0.15 in total.
The ingot is then generally homogenized at a temperature between 500 ° C and 590 ° C, preferably at a temperature between 500 ° C and 570 ° C and preferably between 540 ° C and 560 ° C, generally over a period of 0 , 5 to 24 hours, for example for at least 2 hours and preferably for at least 4 hours. In one embodiment, the homogenization is carried out at a temperature less than or equal to 555 ° C. Homogenization can be achieved by gradually increasing the temperature, in one or more steps, to avoid burns.
After homogenization, the ingot is cooled at a cooling rate situated in a range from 150 ° C / h to 2000 ° C / h directly at the starting temperature of the hot rolling. The cooling rate is at least 200 ° C / h, preferably at least 250 ° C / h and preferably at least 300 ° C / h. In one embodiment, the cooling rate is at most 1500 ° C / h, or at most 1000 ° C / h or at most
500 ° C / h. The cooling rate of the invention is preferably obtained at mid-thickness and / or a quarter of the thickness of the ingot and / or on average in the ingot, generally between the homogenization temperature and the hot rolling temperature. and preferably in the temperature range between 500 ° C and the hot rolling temperature. A device such as the cooling installation described in patent application WO2016 / 012691, as well as the method described therein, are suitable for cooling the ingot. When the thickness of the ingot is at least 250 mm or at least 350 mm and preferably at least 400 mm, or even at least 500 mm or 600 mm, the ingot preferably having a width of 1000 to 2000 mm for a length of 2000 to 8000 mm, it is advantageous that a temperature difference of less than 40 ° C and preferably less than 30 ° C on the whole ingot cooled from the homogenization temperature is obtained at the starting temperature of hot rolling at the time when hot rolling begins. If a temperature difference of less than 40 ° C. and preferably less than 30 ° C. is not obtained, the desired starting temperatures for hot rolling cannot be obtained locally in the ingot, and the surface quality and the properties desired mechanical properties may not be achieved. Preferably, the cooling is carried out in at least two phases: a first sprinkling phase during which the ingot is cooled in a chamber comprising rows of nozzles for spraying the coolant or spraying under pressure, divided between the upper and lower parts of said chamber so as to sprinkle the two large upper and lower surfaces of the ingot, and an additional phase of thermal equalization in the open air in a tunnel preferably provided with reflective internal walls, for a period of 2 to 30 minutes depending on the size of the ingot and the value of cooling.
Preferably, the duration of the thermal equalization phase is less than 10 minutes. Preferably, the small areas on the edges of the ingot are not cooled by direct spraying of the coolant or by spraying under pressure. Preferably, the watering and thermal equalization phases are repeated in the case of very thick ingots and for an overall average cooling greater than 80 ° C. Preferably, the coolant, including that which is sprayed, is water, and preferably deionized water. Preferably, the head and the foot of the ingot, generally the 300 to 600 mm situated at the ends, are less cooled than the rest of the ingot so as to keep the head and the foot hot, which constitutes a favorable configuration for engaging the ingot during reversible hot rolling. In one embodiment, the cooling of the head and the foot is modulated by activating or deactivating the rows of nozzles. In another embodiment, the cooling of the head and the foot is modulated by the presence of screens. Preferably, the sprinkling and not thermal equalization phases are repeated, and the head and the foot of the ingot, generally the 300 to 600 mm located at the ends, are cooled differently from the rest of the ingot in at least one watering chambers. Preferably, the longitudinal thermal uniformity of the ingot is improved by the relative movement of the ingot relative to the sprinkler system: the ingot passes or moves in an alternating movement opposite a fixed sprinkler system, or vice versa. Preferably, the transverse thermal uniformity of the ingot is ensured by modulating the sprinkling in the width of the ingot, by activating or deactivating the nozzles or the spray nozzles, or by sieving said sprinkling. Advantageously, the ingot moves, horizontally in the watering chamber, at a speed greater than or equal to 20 mm / s.
The cooling rate after homogenization is controlled in this way so that if the cooling rate is too low, too large and potentially numerous Mg-Si particles will tend to precipitate and the product could be dissolved. prove to be difficult, and if the cooling rate is too high, too fine and potentially few Mg-Si-based particles are liable to precipitate and recrystallization of the product could prove difficult at the end of hot rolling. In the present invention, the method making it possible to obtain the temperature at mid-thickness and / or a quarter of the thickness of the ingot and / or on average in the ingot may consist in using and measuring an ingot with an integrated thermocouple, or to perform a calculation using a heat transfer model.
The cooling rate is adjusted so that the duration of keeping at the hot rolling temperature is less than 15 min, preferably less than 10 min and preferably less than 5 min.
During the hot rolling step, setting the winding temperature after hot rolling is important. With the present invention, the above-mentioned cooling after homogenization makes it possible to obtain an appropriate distribution of the particles and to carry out the hot rolling of an ingot with particles of controlled size which do not hinder the promoting action and the migration of the joints. grain of the recrystallization, and which are easy to put in solution. Here, the appropriate setting of the winding temperature of the hot-rolled thin sheet obtained produces recrystallization at the exit of the hot-rolling, and makes it possible to obtain a recrystallized structure which forms the basis of the structure of the material for improvement. surface quality.
Preferably, the starting temperature for hot rolling (HRST) is between 350 ° C and 450 ° C. In certain embodiments, the starting temperature of the hot rolling is at least 370 ° C., or at least 375 ° C., or at least 380 ° C., or at least 385 ° C., or at least 390 ° C, or at least 395 ° C, or at least 400 ° C or at least 405 ° C. In certain embodiments, the starting temperature of the hot rolling is at most 445 ° C, or at most 440 ° C, or at most 435 ° C, or at most 430 ° C, or not more than 425 ° C or not more than 420 ° C. The initial temperature of hot rolling is generally understood to mean the temperature at mid-length and at mid-thickness of the ingot; however, since the temperature difference within the ingot is small, the starting temperature of the hot rolling can be measured at half the width on the surface using a contact probe. Preferably, the ingot is hot rolled to a final thickness and wound to the final thickness with conditions allowing a recrystallization rate of at least 90% to be obtained at the final thickness after hot rolling. Preferably, the ingot is hot rolled to a final thickness and wound to the final thickness with conditions allowing a recrystallization rate of at least 98% to be obtained, a recrystallization rate of approximately 100% being generally obtained at the final thickness after hot rolling. At least 90% or 98% recrystallization respectively means that the recrystallization rate measured at at least three points over the width of the strip obtained after hot rolling has a minimum value of at least 90% or 98%. Generally, recrystallization varies over the thickness of the thin sheet.
In order to obtain recrystallization to the final thickness after hot rolling, the exit temperature from hot rolling, also called winding temperature, is at least 300 ° C. In one embodiment, the exit temperature from hot rolling is at least 310 ° C, or at least 330 ° C, or at least 332 ° C, or at least 335 ° C, or at least 337 ° C, or at least 340 ° C, or at least 342 ° C or at least 345 ° C.
In one embodiment, the exit temperature from the hot rolling is at most 380 ° C. The reduction in thickness during the last pass of hot rolling can also affect the rate of recrystallization and the final properties of the product. Preferably, the reduction in thickness during the last pass of the hot rolling is at least 25%. In one embodiment, it is at least 27%, or at least 30% or at least 32%. In one embodiment, it is at most 60%. The final thickness after hot rolling is generally between 2 and 13 mm.
Against all expectations, the present inventors have observed that by controlling the hot rolling temperatures, in particular the relationship between the starting temperature of the hot rolling (HRST) and the exit temperature of the hot rolling, and / or by controlling the grain size after winding, it is possible to obtain a high surface quality of the final product. In particular, when the exit temperature from hot rolling is between 1.2 * HRST - 135 ° C and 1.2 * HRST - 109 ° C and / or adjusted so as to obtain an average grain size in the section L / TC between mid-thickness and a quarter of the thickness, according to the intercept method of ASTM E-112, of less than 160 µm in the longitudinal direction, the surface quality is considerably improved . Preferably, the exit temperature from the hot rolling is at least
1.2 * HRST - 123 ° C and / or at most 1.2 * HRST - 115 ° C and / or adjusted so as to obtain an average grain size in the L / TC section between mid-thickness and a quarter of the thickness, according to the intercept method of ASTM E-112, of less than 150 µm in the longitudinal direction. With regard to the surface quality, with a method of the invention and according to VDA recommendation 239-400, a value less than 4.5, preferably less than 4.0, or even less than 3, 8 can be obtained.
Cold rolling is carried out directly after hot rolling to further reduce the thickness of the thin aluminum sheets. Thanks to the process of the invention, no annealing and / or solution treatment after hot rolling or during cold rolling is necessary to obtain sufficient properties in terms of resistance, aptitude for setting shape, surface quality and corrosion resistance. Preferably, no annealing and / or solution treatment after hot rolling or during cold rolling is carried out. The thin sheet obtained directly after cold rolling is called cold rolled thin sheet. The thickness of the cold-rolled thin sheet is generally between 0.5 and 2 mm.
In one embodiment, the reduction by cold rolling is at least 50%, or at least 65%, or at least 70%, or at least 75% or at least 80% . Generally, the reduction by cold rolling is about 80%.
Advantageous embodiments of the reduction by cold rolling can make it possible to obtain an improvement in the mechanical properties and / or to obtain an advantageous grain size for the surface properties such as the surface quality.
Cold-rolled thin sheet is advantageous at least because it is easy to dissolve, while ensuring a high surface quality and good mechanical properties after dissolving.
After cold rolling, the cold-rolled thin sheet is advantageously subjected to a solution treatment and additional quenching in a continuous annealing line. Preferably, the continuous annealing line operates in such a way that the holding time equivalent to 540 ° C., ί ^ °°, is less than 45 s, preferably less than 35 s and more preferably less than 25 s, the duration of equivalent hold being calculated using the equation
7-540 ° ^L eq - I dt. exp 'time spent in the oven
Q i ___ * ___ 3 — J]
R v ° ^c (t) + 273 540 + 273 /
Q being an activation energy of 146 kJ / mol and R =
8.314 J / mol
Generally, the continuous annealing line operates in such a way that the heating speed of the thin sheet is greater than or equal to 10 ° C / s for a metal temperature greater than 400 ° C, the time spent above 520 ° C. is between 5 s and 25 s, and the quenching speed is greater than or equal to 10 ° C / s, preferably greater than or equal to 15 ° C / s for a thickness of 0.9 to 1.1 mm. The preferred temperatures for the solution treatment are close to the solidus temperatures, namely generally greater than 540 ° C. and less than 570 ° C. The winding temperature after the solution treatment is preferably between 50 ° C and 90 ° C, and preferably between 60 ° C and 80 ° C.
After the dissolution treatment and the quenching, the thin sheet can be returned so as to reach the metallurgical state T4, cut and folded until obtaining its final shape, painted and hardened by baking.
The process of the invention is particularly useful for the production of thin sheets intended for the automotive industry which combine a high tensile strength and a formability suitable for cold stamping operations, as well excellent surface quality and high corrosion resistance with high productivity.
EXAMPLES
Example 1
In this example, three ingots made from an alloy consisting of the following elements, in% by weight: Si: 0.9; Mg: 0.4; Mn 0.1; Fe 0.2; Cu 0.08; Ti 0.04; the remainder consisting of aluminum and unavoidable impurities of at most 0.05% each and 0.15% in total, are molded into 520 mm thick plates and then transformed.
The ingots are homogenized at 560 ° C for 2 hours. After homogenization, the ingots are cooled at a half-thickness cooling rate of 300 ° C / h directly to the starting temperature of the hot rolling. A temperature difference of less than 30 ° C over the whole ingot cooled from the homogenization temperature is obtained. When this temperature difference is reached, hot rolling begins immediately. A device as described in patent application WO2016 / 012691 is used to cool the ingots after homogenization and obtain a temperature difference of less than 30 ° C over the whole of the ingot cooled from the homogenization temperature.
The ingots are hot rolled under the conditions presented in Table 1. The hot rolling mill comprises a reversible rolling mill and a tandem rolling mill with 4 cages, the designation of the cages going from C3 to C6 so that the rolling in the cage C6 corresponds at the last pass of hot rolling.
Table 1 - Parameters of hot rolling
Lingo t Hot rolling start temperature [° C] Hot rolling outlet temperature [° C] reduction in cage C6 [%] 1.2 * HRST - 135 1.2 * HRST - 109 1 415 358 37% 363 389 2 400 359 38% 345 371
3 384 364 33% 326 352
The recrystallization rate of the strips after hot rolling is 100%.
The strips are subjected to an additional cold rolling so as to obtain thin sheets having a final thickness of 1 mm. Thin sheets are subjected to a setting treatment
solution, so the hold time equivalent to 540 ° Cannealing about 30 continuous. s, and at one soak in a line of The quality of surface is measured accordance at the
VDA recommendation 239-400. In particular, the thin sheet sample is subjected to a plastic pre-deformation of 10%, transversely to the direction of rolling. The surfaces are cleaned and a replica of the pre-deformed surface is created by moistening the surface with water, applying an adhesive strip, removing air bubbles and the water located under the strip, drying the strip using a soft cloth, grinding the strip using a grinding tool moved back and forth twice at constant pressure and transversely to the direction of rolling, removing the replica from the surface and transferring it to a black background, removing air bubbles and water, drying the strip with a cloth. The replicas are digitized. The scanning resolution is 300 dpi in "shades of gray". The evaluation and determination of the “value of the RK lineage” of the surface quality were carried out in accordance with the instructions and the macro described in recommendation 239-400 of the VDA. A low RK value corresponds to a high surface quality.
The RK values are presented in Table 2
Table 2 - RK values
Ingot RK 1 5.1 2 3, 5 3 5.4
The surface quality of the ingot 2 according to the invention is significantly improved compared to the ingots 1 and 3.
The tensile elasticity limit at 0.2% and the breaking strength of thin sheets in metallurgical state T4 (after 6 days of curing) and thin sheets hardened by baking (2% of tension and 20 min at 185 ° C) from the thin sheets returned to the T4 state is determined in the transverse direction using methods known to a person skilled in the art. Tensile tests are carried out in accordance with ISO / DIS 6892-
1. The results are presented in Table 3
Table 3 - Mechanical properties
T4 Hardened by bakingTensile strength TL (MPa) Breaking strength TL (MPa) Tensile strength TL (MPa) 1 92 207 201 2 96 208 211 3 102 214 224
Example 2
In this example, six ingots made from an alloy consisting of the following elements, in% by weight: Si: 1.3; Mg: 0.3;
Μη 0.1; Fe 0.2; Cu 0.09; Ti 0.03; the remainder consisting of aluminum and unavoidable impurities of at most 0.05% each and 0.15% in total, are molded into 520 mm thick plates and then transformed.
The ingots are homogenized and cooled as in the example
1.
The ingots are hot rolled under the conditions presented in Table 4. The hot rolling mill comprises a reversible rolling mill 10 and a tandem rolling mill with 4 stands, the designation of the stands going from C3 to C6 so that the rolling in the stand C6 corresponds to the last pass of hot rolling.
Table 4 - Parameters of hot rolling
Lingo t Starting temperature for hot rolling [° C] Hot rolling exit temperature [° C] reduction in the cageC6 [%] 1.2 * HRST - 135 1.2 * HRST - 109 Grain size after hot rolling (pm) 4 414 375 34 362 388 146 5 397 352 35 341 3676 402 364 37 347 373 130 7 386 344 35 328 354 128 8 430 345 36 381 407 182 9 397 370 34 341 367 168
The recrystallization rate of the strips after hot rolling is 100%. An average grain size in the L / TC section between mid-thickness and a quarter of the thickness, according to the intercept method of ASTM E-112, is measured once the coil is cooled. The results are also presented in Table 4.
The strips are subjected to an additional cold rolling so as to obtain thin sheets having a final thickness of 1 mm. The thin sheets are subjected to a solution treatment, so that the holding time equivalent to 540 ° C. is approximately 30 s, and to quenching in a continuous annealing line.
The surface quality is measured in accordance with VDA recommendation 239-400, as in Example 1.
The RK lineage values are presented in Table 5
Table 5 - RK values
Ingot RK 4 3.4 5 3, 6 6 3.2 7 3.5 8 8.1 9 5.0
The surface quality of ingots 4 to 7 according to the invention is significantly improved compared to ingots 8 and 9.
The tensile elasticity limit at 0.2% and the breaking strength of thin sheets in metallurgical state T4 (after 6 days of curing) and thin sheets hardened by baking (2% of tension and 20 min at 185 ° C) from the thin sheets returned to the T4 state is determined in the transverse direction using methods known to a person skilled in the art. Tensile tests are carried out in accordance with ISO / DIS 689220 1. The results are presented in Table 6
Table 6 - Mechanical properties
T4 Hardened by bakingTensile yield strength TL(MPa) Breaking strength TL (MPa) Tensile strength TL (MPa)
4 100 211 208 5 93 211 206 6 105 226 225 7 99 218 205 8 102 220 224 9 98 217 206
Example 3
In this example, three ingots made from an alloy consisting of the following elements, in% by weight: Si: 0.75; Mg: 0.65; Mn 0.1; Fe <0.16; Ti 0.04; the remainder consisting of aluminum and unavoidable impurities of at most 0.05% each and 0.15% in total, are molded into sheets 500 mm thick and then processed.
The ingots are homogenized and cooled as in the example
1.
The ingots are hot rolled under the conditions presented in Table 7. The hot rolling mill comprises a reversible rolling mill and a tandem rolling mill with 4 cages, the designation of the cages going from C3 to C6 so that the rolling in the cage C6 corresponds at the last pass of hot rolling.
Table 7 - Parameters of hot rolling
Lingo t Hot rolling start temperature [° C] Hot rolling outlet temperature [° C] reduction in cage C6 [%] 1.2 * HRST - 135 1.2 * HRST - 109 10 402 360 37 347 373 11 404 369 37 350 376 12 391 377 39 334 360
The recrystallization rate of the strips after hot rolling is 100%.
The strips are subjected to additional cold rolling so as to obtain thin sheets having a final thickness of approximately 1 mm. The thin sheets are subjected to a solution treatment, so that the holding time equivalent to 540 ° C. is approximately 30 s, and to quenching in a continuous annealing line.
Surface quality is measured in accordance with VDA recommendation 239-400, as in Example 1.
The RK lineage values are presented in Table 8
Table 8 - RK values
Ingot RK 10 3.2 11 3.9 12 5.0
The surface quality of the ingots 10 and 11 according to the invention is significantly improved compared to the ingot 12.
The tensile elasticity limit at 0.2% and the breaking strength of thin sheets in metallurgical state T4 (after 6 days of curing) and thin sheets hardened by baking (2% of tension and 20 min at 185 ° C) from the thin sheets returned to the T4 state is determined in the transverse direction to. Using methods known to those of ordinary skill in the art. Tensile tests are carried out in accordance with ISO / DIS 6892-
1. The results are presented in Table 9
Table 9 - Mechanical properties
T4 Hardened by baking
Tensile yield strength TL(MPa) Breaking strength TL (MPa) Tensile strength TL (MPa) 10 114 223 250 11 111 221 247 12 105 212 223

权利要求:
Claims (10)
[1" id="c-fr-0001]
1. Process for manufacturing a thin sheet of aluminum alloy of the 6xxx series comprising the following steps:
- homogenization of an ingot made from an aluminum alloy of the 6XXX series preferably consisting of the following elements, in weight content: 0.3 to 1.5% of
If, 0.1 to 1.2% of Mg and 0.5% or less of Cu, Mn 0.03 0.5% and / or Cr 0.01 - 0.4%, Fe 0.03 to 0, 4%, Zn at most
0.5%, V at most 0.2%, Zr at most 0.2%, Ti at most
0.1%, the balance consisting of aluminum and unavoidable impurities of not more than 0.05% each and 0.15% in total,
- cooling of the homogenized ingot at a cooling rate located in the range between 150 ° C / h and 2000 ° C / h directly to a starting temperature of hot rolling (HRST),
hot rolling of the ingot to a final thickness and winding at the final thickness and at an exit temperature from hot rolling with conditions allowing at least 90% recrystallization to be obtained, said HRST being between 350 ° C and 450 ° C and the exit temperature of the hot rolling being equal to or greater than 300 ° C and between 1.2 * HRST - 135 ° C and
1.2 * HRST - 109 ° C and / or adjusted so as to obtain an average grain size in the L / TC section between mid-thickness and a quarter of the thickness, according to the intercept method of the standard ASTM E-112, less than 160 µm in the longitudinal direction,
- cold rolling in order to obtain a cold-rolled thin sheet.
[2" id="c-fr-0002]
2. Method according to claim 1, characterized in that the reduction in thickness during the last pass of the hot rolling is at least 25%.
[3" id="c-fr-0003]
3. Method according to any one of claims 1 to 2, characterized in that the reduction by cold rolling is at least 50%.
[4" id="c-fr-0004]
4. Method according to any one of claims 1 to 2, characterized in that the exit temperature from the hot rolling is at least 1.2 * HRST - 123 ° C or at most
1.2 * HRST - 115 ° C or adjusted so as to obtain an average grain size in the L / TC section between mid-thickness and a quarter of the thickness, according to the intercept method of ASTM E -112, less than 150 µm in the longitudinal direction.
[5" id="c-fr-0005]
5. Method according to any one of claims 1 to 4, characterized in that the starting temperature of the hot rolling is at least 390 ° C.
[6" id="c-fr-0006]
6. Method according to any one of claims 1 to 5, characterized in that the cold-rolled thin sheet is subjected to a solution treatment and additional quenching in a continuous annealing line.
[7" id="c-fr-0007]
7. Method according to claim 6, characterized in that the continuous annealing line operates in such a way that the holding time equivalent to 540 ° C, tfg °°, is less than 45 s, preferably less than 35 s and more preferably less than 25 s, the equivalent holding time being calculated using the equation t ⁵⁴⁰ ° = ^L eq I ^J time spent in the oven
Q being an activation energy of 146 kJ / mol and R = 8.314 J / mol.
[8" id="c-fr-0008]
8. Method according to claim 6 or claim 7, characterized in that after the solution treatment and quenching, the thin sheet is returned so as to reach the metallurgical state T4, cut and bent until its final form, painted and hardened by cooking.
[9" id="c-fr-0009]
9. Method according to any one of claims 1 to 8, characterized in that the thickness of the ingot is at least 250 mm, the ingot preferably having a width of 1000 to 2000 mm for a length of 2000 to 8000 mm, and in that a temperature difference of less than 40 ° C over the whole ingot cooled from the homogenization temperature is obtained at the starting temperature of the hot rolling.
[10" id="c-fr-0010]
10. Method according to any one of claims 1 to
9, characterized in that the cooling is carried out in at least two phases: a first sprinkling phase during which the ingot is cooled in a chamber comprising rows of nozzles for spraying the coolant or spraying under pressure , divided between the upper and lower parts of said chamber so as to spray the two large upper and lower surfaces of said ingot, and a complementary phase of thermal equalization in the open air in a tunnel provided with reflecting internal walls, for a period 2 to 30 minutes.

类似技术:

---

公开号 | 公开日 | 专利标题

---

FR3076837A1|2019-07-19|PROCESS FOR MANUFACTURING 6XXX ALUMINUM ALUMINUM THIN ALLOYS WITH HIGH SURFACE QUALITY

---

EP2984195B1|2019-01-16|Process of manufacturing a rolled al-cu-li sheet with improved formability and corrosion resistance

---

CA2832085C|2019-02-26|Aluminium-copper-magnesium alloys that perform well at high temperature

---

EP1488018B1|2008-09-24|Al-mg alloy products for a welded construction

---

FR2841263A1|2003-12-26|PROCESS FOR PRODUCING A HIGH-STRENGTH BALANCED AL-Mg-Si ALLAGEN PRODUCT, AND WELDABLE PRODUCT AND AIRCRAFT COATING MATERIAL OBTAINED BY SUCH A METHOD

---

FR2876118A1|2006-04-07|AL-ZN ALLOY PRODUCT OF HIGH STRENGTH AND HIGH STRENGTH, AND METHOD OF MANUFACTURING THE SAME

---

FR2935397A1|2010-03-05|ALUMINUM ALUMINUM ALLOY ALLOY WELDING AND VERY RESISTANT, AND PRODUCED IN SUCH ALLOY

---

EP2981632B1|2017-08-02|Thin sheets made of an aluminium-copper-lithium alloy for producing airplane fuselages

---

CN109477194B|2021-12-21|Method for preparing 6XXX aluminum plate

---

CA2915411A1|2015-01-29|Extrados structural element made from an aluminium copper lithium alloy

---

CA2954830C|2019-02-12|Hot-rolled steel sheet and associated production process

---

CA3085811A1|2019-06-27|Improved process for manufacturing sheets made of aluminium-copper-lithium alloy for aircraft fuselage manufacture

---

EP2245203A1|2010-11-03|Austenitic stainless steel sheet and method for making said sheet

---

FR2857981A1|2005-01-28|Thin sheet or strip of aluminum alloy for bottle caps and wrapping foil has a thickness of less than 200 microns, is essentially free of manganese, and has increased mechanical strength

---

FR2816534A1|2002-05-17|Manufacture of clad strip used for manufacturing brazed heat exchanger, involves homogenizing plate made of core alloy before rolling

---

EP1349965B1|2005-02-16|Rolled or extruded aluminium al-mn alloy products with improved corrosion resistance

---

WO1998052707A1|1998-11-26|Method for making aluminium alloy strips by continuous thin gauge twin-roll casting

---

FR3053979B1|2019-06-28|FLANS IN ALUMINUM ALLOYS WITH A LOCAL FLASH RECLA

---

FR2889852A1|2007-02-23|Aluminum alloy for aircraft, land vehicle and marine use contains small quantities of magnesium, manganese and other elements for high strength and corrosion resistance

---

WO2021064320A1|2021-04-08|Aluminum alloy precision plates

---

JP4708555B2|2011-06-22|Continuous solution quenching method for rolled aluminum alloy sheets with excellent formability and flatness

---

CA3105902A1|2020-01-23|Process for manufacturing thin sheets made of 7xxx aluminum alloy suitable for shaping and assembly

---

FR2748035A1|1997-10-31|ALUMINUM-SILICON-MAGNESIUM ALLOY FOR AUTOMOTIVE BODYWORK

---

FR2846340A1|2004-04-30|Fabrication of an improved aluminium alloy strip for the production of high quality culinary utensils

---

FR2836929A1|2003-09-12|A1-MG ALLOY SHEET OR TAPE FOR THE MANUFACTURING OF BENDED PARTS WITH LOW BENDING RADIUS

同族专利:

---

公开号 | 公开日

---

KR20200106166A|2020-09-11|

---

FR3076837B1|2020-01-03|

---

US20200340091A1|2020-10-29|

---

WO2019141693A1|2019-07-25|

---

CN111556903A|2020-08-18|

---

EP3740599A1|2020-11-25|

---

CA3086313A1|2019-07-25|

---

JP2021510774A|2021-04-30|

引用文献:

---

公开号 | 申请日 | 公开日 | 申请人 | 专利标题

---

EP0786535A1|1994-02-16|1997-07-30|Sumitomo Light Metal Industries, Ltd.|Method of manufacturing aluminum alloy plate for molding|

---

US6652678B1|1999-03-01|2003-11-25|Alcan International Limited|AA6000 aluminum sheet method|

---

US20150354044A1|2013-02-13|2015-12-10|Kabushiki Kaisha Kobe Seiko Sho |Aluminum alloy sheet with excellent baking paint hardenability|

---

JP2015067857A|2013-09-27|2015-04-13|株式会社Uacj|Al-Mg-Si-BASED ALUMINUM ALLOY SHEET FOR AUTOMOBILE PANEL AND MANUFACTURING METHOD THEREFOR|

---

JPS59685B2|1974-11-13|1984-01-07|Toyota Motor Co Ltd|

---

KR100870164B1|2001-03-28|2008-11-25|스미토모 게이 긴조쿠 고교 가부시키가이샤|Aluminum alloy sheet with excellent formability and paint bake hardenability|

---

JP4383039B2|2001-11-30|2009-12-16|トヨタ自動車株式会社|Method for producing aluminum alloy sheet with excellent bending workability|

---

JP3833574B2|2002-06-07|2006-10-11|株式会社神戸製鋼所|Aluminum alloy sheet with excellent bending workability and press formability|

---

JP2006241548A|2005-03-04|2006-09-14|Sumitomo Light Metal Ind Ltd|Al-Mg-Si ALLOY SHEET SUPERIOR IN BENDABILITY, MANUFACTURING METHOD THEREFOR, AND AUTOMOTIVE SKIN PLATE OBTAINED FROM THE SHEET|

---

US8366846B2|2008-03-31|2013-02-05|Kobe Steel, Ltd.|Aluminum alloy sheet with excellent post-fabrication surface qualities and method of manufacturing same|

---

JP5406745B2|2009-03-19|2014-02-05|株式会社神戸製鋼所|Aluminum alloy sheet with excellent ridging marks during molding|

---

JP5683193B2|2010-09-30|2015-03-11|株式会社Uacj|Aluminum alloy rolled sheet for forming with excellent ridging resistance and method for producing the same|

---

JP5865582B2|2010-09-30|2016-02-17|株式会社Uacj|Aluminum alloy plate for forming process excellent in bending workability and manufacturing method thereof|

---

FR3024058B1|2014-07-23|2016-07-15|Constellium France|METHOD AND EQUIPMENT FOR COOLING|

---

EP3950987A1|2015-01-12|2022-02-09|Novelis, Inc.|Highly formable automotive aluminum sheet with reduced or no surface roping and a method of preparation|JP6208389B1|2016-07-14|2017-10-04|株式会社Uacj|Method for producing rolled aluminum alloy material for forming comprising aluminum alloy having excellent bending workability and ridging resistance|

---

CN110735073B|2019-11-04|2020-12-18|苏州大学|High-quality 6-series aluminum alloy extruded casting blank and preparation method thereof|

---

WO2021168064A1|2020-02-19|2021-08-26|Novelis Inc.|Control of aluminum alloy microstructure for improved corrosion resistance and bonding performance|

---

WO2022026825A1|2020-07-31|2022-02-03|Arconic Technologies Llc|New 6xxx aluminum alloys and methods for producing the same|

法律状态:
2019-01-25| PLFP| Fee payment|Year of fee payment: 2 |

---

2019-07-19| PLSC| Publication of the preliminary search report|Effective date: 20190719 |

---

2020-01-27| PLFP| Fee payment|Year of fee payment: 3 |

---

2021-01-25| PLFP| Fee payment|Year of fee payment: 4 |

---

2022-01-25| PLFP| Fee payment|Year of fee payment: 5 |

优先权:

---

申请号 | 申请日 | 专利标题

---

FR1850349|2018-01-16|

---

FR1850349A|FR3076837B1|2018-01-16|2018-01-16|PROCESS FOR THE MANUFACTURE OF THIN SHEETS OF HIGH-SURFACE ALUMINUM 6XXX ALLOY|FR1850349A| FR3076837B1|2018-01-16|2018-01-16|PROCESS FOR THE MANUFACTURE OF THIN SHEETS OF HIGH-SURFACE ALUMINUM 6XXX ALLOY|

---

EP19700598.6A| EP3740599A1|2018-01-16|2019-01-15|Method of making 6xxx aluminium sheets with high surface quality|

---

KR1020207021287A| KR20200106166A|2018-01-16|2019-01-15|Method for manufacturing 6XXX aluminum sheet with excellent surface quality|

---

JP2020559027A| JP2021510774A|2018-01-16|2019-01-15|Manufacturing method of 6XXX aluminum sheet with high surface quality|

---

CN201980007438.3A| CN111556903A|2018-01-16|2019-01-15|Method for producing 6XXX aluminium sheets with high surface quality|

---

CA3086313A| CA3086313A1|2018-01-16|2019-01-15|Method of making 6xxx aluminium sheets with high surface quality|

---

US16/962,036| US20200340091A1|2018-01-16|2019-01-15|Method of making 6xxx aluminium sheets with high surface quality|

---

PCT/EP2019/050978| WO2019141693A1|2018-01-16|2019-01-15|Method of making 6xxx aluminium sheets with high surface quality|